Barium concentration and isotopic data from SAFe, collected during the 2nd GEOTRACES Intercalibration cruise, KN195-08, on R/V Knorr in the eastern North Pacific during May 2009.
Samples were collected on the GEOTRACES carousel, filtered to 0.2 μm or 0.45 μm (depending on filter type), acidified to pH ≈ 2 with hydrochloric acid, and stored for several years prior to processing. Aliquots containing five milliliters of seawater were cleanly subsampled from each sample, weighed, and an appropriate quantity of ¹³⁶Ba–¹³⁵Ba double spike added. Following spike–sample equilibration, barium was co-precipitated with calcium carbonate via dropwise addition of sodium carbonate. The resultant precipitate was dissolved in hydrochloric acid and twice passed through cation-exchange columns to purify Ba from matrix elements.
Samples were aspirated, desolvated, and analyzed using a 100 μL/min nebulizer, Aridus II desolvation system, and ThermoFisher Neptune multi-collector ICP-MS, respectively. All instrumentation was sitated at the WHOI Plasma Facility. Barium-isotopic compositions were calculated from simultaneous monitoring of ion beams corresponding to m/z 131 (Xe, xenon), 135 (Ba), 136 (Xe; Ba; Ce, cerium), 137 (Ba), 138 (Ba; La, lanthanum; Ce), 139 (La) and 140 (Ce).
Problem report:
Sample 4722 (surface) unclear if sample was filtered, and—if so—what filter cutoff was used.
Horner, T. (2019) Barium concentration and isotopic data from SAFe, collected during the 2nd GEOTRACES Intercalibration cruise (R/V Knorr KN195-08) in the eastern North Pacific during May 2009. Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version 2) Version Date 2019-08-06 [if applicable, indicate subset used]. doi:10.1575/1912/bco-dmo.770368.2 [access date]
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